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If you mean installing hardened exhaust valve inserts, it depends on several factors. How much use the engine is going to receive and in what service....racing or just driving; how are the inserts to be installed; what type of inserts will be installed; what type of exhaust valves will be used with the inserts; are the exhaust valves sodium cooled; are valve rotators used, is the engine due for a refreshing and the heads are coming off anyway.If you have easy access to 100ll avgas, use that as above. Otherwise, for simplicity sake when taking the care anywhere, I'd have a valve job done w hardened exhaust seats. Really not that expensive and never have to worry about it afterwards.
There are literally thousands of gallons of octane booster sold annually because of "its easier to use" or I can't find av gas or "my buddy swears by it" rule. B4 committing to use a booster, research the product. The quantity of booster needed to raise the octane percentage by a significant amount is much larger than expexted.....one can, typically 12-16 ounces, raises the octane rating by 0.5 point. Basically, one can per 10-15 gallons of 93 octane pump gas, will do almost nothing to increase the overall octane. Plus it introduces the manganese salts which will cause premature spark plug fouling......use it at your own descreshion.....your car, your $$$$. Just my opinion of course.
BOB RENTON