Go to 521 restorations website and see the pictures of grills they have done, it will give you a good idea of what you want.
I have played with the paints, paid the $25 a can some companies ask, also had some stuff custom mixed and sprayed it through the detailing gun base clear and ss. But now I just keep it simple that 621 from pk is just as close as anything else I have used, if you are doing an oem gold car, sure go nuts, get it perfect (or what some may think is perfect, who knows what it looked like on day 1? even NOS in the box parts change color a bit after 50 years on the shelf).
As far as the black goes, I have seen them 3 different ways
all silver
black center with silver around lights and rim (I prefer that one)
and black center but with silver on each fin
For the black on grills I use #616 its a satin black, some people like a gloss black on the grills, but I think the satin is closer to what I expect them to look like, that paint doesn't say satin or matte or gloss, but it sprays out a nice satin sheen.
PS while in the garage looking at the numbers on the cans, I found a plastikote adhesion promotor I have used and forgot about, it worked well on some 71 grills I did #469 not sure if its still available amazon is a good source if you cant get it local.
I hope this helps, for $25 of paint products, try spraying them on some card board or grills pieces and see what you think compared to what is left on your grille. I have done a lot of grills this way and they come nice, I can take some pics this week of a set I have been working on, should paint them by the weekend, depends how I feel. been having some chest pains, maybe working on 4th cardiac event lol, don't get old guys, all down hill after 60