That wasn't 'caused' by anything in your engine, that was ground on by whoever disassembled your heads so the valve would come out through the guide. They mushroom sometimes and won't come out through the guide, so I usually use a file to straighten the sides of the valve stem tip, but someone was in a hurry and used a dremmel it looks like.Here is a better picture. So what do you think caused that. The rocker arms don't have a scratch on them.
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You really should take more time inspecting your stuff before you pay the man and especially while assembling. Not trying to bust your balls, just saying.