I am getting cranking compression pressures of 210 to 220 PSI. A 451 cubic inch at 13 to 1 C/R. Last fuel mix was 3 gallons of 91 octane Premium, (all the premium is 91 octane in Denver, as opposed to 93 at lower elevations). 2 gal of E 85 which is 105 octane, and 1 gallon of 100 Sunoco race fuel. This mix should be about 97 octane. The only time it would ping, was at wide open throttle going up a steep hill at 70 MPH. The engine was fairly warm. Got it to the track, cooled it down to about 130 degrees coolant temp, and no ping! Engine temp plays a big part in this. Cooler=less tendency to ping.
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Now going 4 jet sizes larger than stock on an 850 CFM Holley double pumper. And with this carb jetted richer than stock, I will use a 50/50 mix of E 85 and 91 Premium with the 850 on the engine. That should work well, and give slightly higher octane numbers. This mix averages out to 98 octane. Bottom line is experiment until you find what works for your particular combination of cam, C/R, Altitude, and fuel choice.