Is the gap or dwell the final setting that you are shooting for with points?
Okay...the final setting would be dwell...for THAT distributor. Should have numbers to shoot for, per the book. But, you might be missing a few things.
New timing chain? Was it installed correctly, timed? Guessing yes, but you should check the basics on it.
If you pull the distributor (not dizzy)(yeah, I know, again!), and look in the hole, you can see the two lifters for #1 cylinder. Why? Turning the engine over by hand, you can check for TDC compression stroke, piston on top, both valves closed (by the lifters), timing mark on the dampner, all that you need to know, to make sure things are right.
Timing mark at 0, piston should be at top, both valves closed. If not, timing is off.
Should know how much advance is 'set' in the distributor, degrees, so when advance is 'all in', it's still in range 34-36. Think that's right, maybe up to 38. Knowing how much advance, minus the full advance, tells you about where the initial should be. Such as full advance at 35, 20 degrees advance in the distributor, gives 15 initial setting.
Usually, both sets of points are set the same, with a feeler gauge, then check dwell, both for each point set, then total. Always worked for me.