The primaries would play a minor role at WOT compared to the power valve and secondaries, which should be dumping more fuel. It sounds like the primaries are doing a pretty darn good job all the way to 4500! But if you have some richer jets then it might tell you something. While you are in there take a quick look at the power valve rating, it's probably a 65. Below it is a restrictor. Also with your carb the secondary jets might or might not be adjustable, but if its lean at WOT then the power valve restrictor and secondary jetting are places to look.
And just be careful about too many high rpm lean blasts which can melt pistons. It sounds like you are really getting close. If timing is ruled out as the cause then fuel delivery, as mentioned by several of us, is the likely culprit.
Totally digging what you're saying here.
I mentioned the 75's because they helped with the old cam a bunch in a similar condition - yep, same motor with a purpleshaft (509) did the same thing at about the same RPM's and the 75's helped some with that. Of course, I had a different power valve in it then, since the vacuum was so much lower with the purpleshaft.
This is all ticking me off because in a couple of former Mopars ('68 Super Bees, both with stock 440's in them) the Holley 3310 right out of the box worked GREAT, along with the Mopar electronic ignition conversion kits.
Figured I was in the same ballpark with this car, so I ordered the exact same carb.
When I put the Comp Cam 270 in it, vacuum was really good again as expected, so I returned the stock 65 power valve and 72 primary jets back in the carb.
It won't hurt a thing to pop the 75's back in there, but the car definitely didn't like the 35 power valve when I swapped cams.
The secondaries aren't adjustable, of course, but I suppose I could swap the secondary metering block out for one with more flow?
Tell me more about the power valve restrictor too. Easy mod? Any harm in trying it?
Thanks!
PS - Guess it shouldn't matter, but in neutral sitting still, the engine happily revs over 5000RPMs, so I'm assuming there's nothing internally in the engine holding this rascal back?