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MOST flammable material won't self ignite with pure oxygen. It still takes a heat source to fire it off, such as the spark striker used with an oxy/acetylene torch. There are a few substances that can spontaneously ignite because they build up heat as they oxidize, but gasoline isn't one of them - it will need a minimum of 495 f. to burn no matter what level of oxygen it's mixed with.Not at all. With oxygen you don't need compression for it to combust. Just introducing oxygen to a combustible substance with cause ignition.
And the materials that will famously catch fire spontaneously, things that oxidize and build up heat faster than it can be radiated away so that they eventually catch fire (oily rags, especially with linseed oil, or damp bales of hay), still take from a few minutes to several hours to catch, not the fractions of a second that would be needed inside an engine.
If you want to experiment and have an oxygen tank, fill a 2 liter soda bottle with 02 and drop various material into it. They'll just sit there, not burning until you add enough heat.