My money is on old gas. Years back I let a car sit for too long without adding fresh gas or fuel conditioner. On one of my 'scheduled' runs, the float was stuck and it flooded the engine with that old gas. At that time, I didn't have the time to drain the tank and put fresh gas in it but a week later, I did but that was too late. That resulted in 2 stuck valves, two bent push rods, and a collapsed lifter......just after one week of letting that stale gas sit in the engine!
If your engine was last started with bad gas and the float was stuck, a running flooding engine, the valves will bounce gas up into the guides. Also, if you are pounding on the valve stems with a brass hammer or a drift, chances are good that you will flare the valve tips. Brass hammers and drifts are not as soft as most think and it's better to use a piece of aluminum instead. If you think the valve tips might be a little bit flared (they can also get that way from the rockers pounding on them), that a small grinder the bevel them before beating them through the guide. And I've never done what 69Bee said but yes, most factory valves are two piece units.