If you are seeing rust from a black pipe air line system, it has Not, been installed properly...
Lets start with, I'm a licensed pipe fitter by trade, I have threaded and installed a couple thousand miles of black pipe in my career. Do all your air lines slope back to your compressor?
Your systems you are referring to, have, inverted trap feeds? Most important feature!!!!
My own shop, 22 years now, with a Devilbiss spay booth, inverted traps and clean out valves, and an air drier, that has sat next to the compressor for 22 years, and never been hooked up. Why, because , NEVER have I even any indication of moisture in my lines. The clean out valves at the bottom of every feed line was a total waste of money , as I have never witnessed any water or debris.
A better option, yeah the next product up, stainless steel!!!!
Plastic, NEVER!!!! , The main reason black pipe is not used for the home hobbiest, is you need to know someone, with a pipe threader, and that will be an expense..